Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes Научная публикация
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Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444 |
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| Вых. Данные | Год: 1991, Том: 40, Номер: 6, Страницы: 1229-1234 Страниц : 6 DOI: 10.1007/bf00961303 | ||
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Реферат:
The reactions of magnesium-cyclopentane with styrene and of 2,4-diphenylmagnesium-cyclopentane with ethylene in the presence of catalytic amounts of Cp2-ZrCl2 leading to the formation of 2-phenylmagnesium-cyclopentane and 2,4-di-phenylmagnesium-cycloheptane, were studied for the first time. It was found that zirconocyclopentanes, are intermediates in this reaction, which are formed both from magnesium-cycloalkanes and from α-olefins and Cp2ZrCl2. A possible mechanism of the reactions studied has been proposed.
Библиографическая ссылка:
Dzhemilev U.M.
, Sultanov R.M.
, Gaimaldinov R.G.
, Tolstikov G.A.
Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991. V.40. N6. P.1229-1234. DOI: 10.1007/bf00961303 РИНЦ OpenAlex
Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991. V.40. N6. P.1229-1234. DOI: 10.1007/bf00961303 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 27 апр. 1990 г. |
Идентификаторы БД:
| РИНЦ: | 31121374 |
| OpenAlex: | W1264967457 |
Цитирование в БД:
| БД | Цитирований |
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| OpenAlex | 9 |