Sciact
  • EN
  • RU

Effect of the structure of substituted propargyl and allyl alcohols on the rate of their liquid phase hydrogenation on a Pd-Ru alloy membrane catalyst Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444
Вых. Данные Год: 1989, Том: 38, Номер: 8, Страницы: 1593-1596 Страниц : 4 DOI: 10.1007/bf00956936
Авторы Karavanov A.N. 1 , Gryaznov V.M. 1
Организации
1 A. V. Topchiev Institute for Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow
Реферат: The rates of hydrogenation of substituted propargyl and allyl alcohols in the liquid phase on a Pd-Ru alloy membrane catalyst are described by a two-parameter Taft equation which takes into account the inductive and steric effects of the substituents. The values of the parameters at 363 K with H2 at atmospheric pressure are: ρ*=−0.20, δ=0.10 and ρ*=−1.1, δ=1.3 respectively.
Библиографическая ссылка: Karavanov A.N. , Gryaznov V.M.
Effect of the structure of substituted propargyl and allyl alcohols on the rate of their liquid phase hydrogenation on a Pd-Ru alloy membrane catalyst
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989. V.38. N8. P.1593-1596. DOI: 10.1007/bf00956936 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 10 мая 1988 г.
Идентификаторы БД:
РИНЦ: 30815312
OpenAlex: W2056749491
Цитирование в БД:
БД Цитирований
OpenAlex 8
Альметрики: