Photochemical oxidation of hydrocarbons by atmospheric oxygen in acetonitrile catalyzed by cyclopentadienyliron complexes Научная публикация
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Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444 |
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| Вых. Данные | Год: 1991, Том: 40, Номер: 7, Страницы: 1492-1494 Страниц : 3 DOI: 10.1007/bf00961264 | ||||
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Реферат:
[(π-ArH)Fe(π-C5H5)]+BF4 −, where ArH is benzene or toluene, catalyzes the photochemical oxidation of hydrocarbons by oxygen in acetonitrile. Cyclohexane and ethylbenzene are oxidized to the alcohol and ketone derivatives, which are formed in different amounts (after gas-liquid chromatography); benzaldehyde is obtained from styrene. The proposed mechanism involves the formation of a peroxide radical from the organometallic complex, which is capable of hydrogen atom abstraction from the alkane.
Библиографическая ссылка:
Druzhinina A.N.
, Shul'pina L.S.
, Shul'pin G.B.
Photochemical oxidation of hydrocarbons by atmospheric oxygen in acetonitrile catalyzed by cyclopentadienyliron complexes
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991. V.40. N7. P.1492-1494. DOI: 10.1007/bf00961264 РИНЦ OpenAlex
Photochemical oxidation of hydrocarbons by atmospheric oxygen in acetonitrile catalyzed by cyclopentadienyliron complexes
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991. V.40. N7. P.1492-1494. DOI: 10.1007/bf00961264 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 11 нояб. 1990 г. |
Идентификаторы БД:
| РИНЦ: | 30845447 |
| OpenAlex: | W2068501458 |
Цитирование в БД:
| БД | Цитирований |
|---|---|
| OpenAlex | 7 |