Effect of high pressure on the composition of stereoisomers of the Diels-Alder reaction between furan and maleic anhydride Научная публикация
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Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444 |
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| Вых. Данные | Год: 1989, Том: 38, Номер: 11, Страницы: 2303-2308 Страниц : 6 DOI: 10.1007/bf01168074 | ||
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Реферат:
The kinetic data on the Diels-Alder reaction between furan and maleic anhydride at atmospheric pressure and 20 and 40°C correspond to a scheme of the process which includes transformation of an endo-isomer into an exo-isomer without preliminary decomposition into the starting substances. The reaction is significantly accelerated by an increase in the pressure, and the rate of formation of the exo-isomer is close to the rate of formation of the endo-isomer both at atmospheric and at high pressure. The endo-isomer is obtained with a high yield (up to 45%) at a high pressure, and this permitted determining the rate constant of its decomposition at atmospheric pressure.
Библиографическая ссылка:
Zhulin V.M.
, Bogdanov V.S.
, Kel'tseva M.V.
, Kabotyanskaya E.B.
, Koreshkov Y.D.
Effect of high pressure on the composition of stereoisomers of the Diels-Alder reaction between furan and maleic anhydride
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989. V.38. N11. P.2303-2308. DOI: 10.1007/bf01168074 РИНЦ OpenAlex
Effect of high pressure on the composition of stereoisomers of the Diels-Alder reaction between furan and maleic anhydride
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989. V.38. N11. P.2303-2308. DOI: 10.1007/bf01168074 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 10 нояб. 1988 г. |
Идентификаторы БД:
| РИНЦ: | 31112880 |
| OpenAlex: | W1987259632 |
Цитирование в БД:
| БД | Цитирований |
|---|---|
| OpenAlex | 5 |