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Changes in the catalytic activity and hydrogen permeability of a palladium-ruthenium alloy membrane catalyst under the influence of reagents Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444
Вых. Данные Год: 1988, Том: 37, Номер: 4, Страницы: 637-640 Страниц : 4 DOI: 10.1007/bf01455465
Авторы Ermilova M.M. 1 , Orekhova N.V. 1 , Skakunova E.V. 1 , Gryaznov V.M. 2
Организации
1 A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow
2 P. Lumumba Friendship of Peoples University, Moscow
Реферат: In the course of catalytic hydrogenation reactions of cyclopentadiene, cyclooctadiene, and isoprene; and in the catalytic hydrogenolysis of propane, all of which proceed at 373–573 K, a.catalytic etching of a palladium-ruthenium membrane catalyst is taking place; it is determined by the nature of the reagents. An oxidative-reductive treatment changes the surface structure, the catalytic activity, and the hydrogen permeability to a much lesser degree than when such a treatment is alternated with actual catalytic reactions. A heat treatment followed by a subsequent rapid cooling from temperatures above the recrystallization temperature, increases significantly the activity of a palladium-ruthenium membrane catalyst in the hydrogenolysis of propane.
Библиографическая ссылка: Ermilova M.M. , Orekhova N.V. , Skakunova E.V. , Gryaznov V.M.
Changes in the catalytic activity and hydrogen permeability of a palladium-ruthenium alloy membrane catalyst under the influence of reagents
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1988. V.37. N4. P.637-640. DOI: 10.1007/bf01455465 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 25 нояб. 1986 г.
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РИНЦ: 30817586
OpenAlex: W2005575051
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OpenAlex 3
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