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Catalytic activity of trivalent lanthanide salts in the chloromethylation of aromatic hydrocarbons Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444
Вых. Данные Год: 1990, Том: 39, Номер: 3, Страницы: 627-628 Страниц : 2 DOI: 10.1007/bf00959602
Авторы Davydov D.V. 1 , Vinogradov S.A. 1 , Beletskaya I.P. 1
Организации
1 M, V. Lomonosov Moscow State University, USSR
Реферат: A study was carried out on the electrophilic substitution reactions in benzene and toluene by the action of ClCH2OCH3 in the presence of trivalent lanthanide salts, LnCl3, where Ln=Ce, Dy, Er, and Sm(O3SCF3)3 as the catalysts, at room temperature over 24 h. These lanthanide salts display the properties of weak but hard Lewis acids. The reaction proceeds exclusively by chloromethylation with the subsequent formation of diarylmethanes.
Библиографическая ссылка: Davydov D.V. , Vinogradov S.A. , Beletskaya I.P.
Catalytic activity of trivalent lanthanide salts in the chloromethylation of aromatic hydrocarbons
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1990. V.39. N3. P.627-628. DOI: 10.1007/bf00959602 РИНЦ OpenAlex
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РИНЦ: 30831663
OpenAlex: W1968196921
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