Metal complexes in catalytic conversion of olefins. 3. Catalytic dimerization of ethylene and propylene by Ni(PPh3)n-Et3Al2Cl3 System Научная публикация
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Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444 |
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| Вых. Данные | Год: 1990, Том: 39, Номер: 3, Страницы: 444-447 Страниц : 4 DOI: 10.1007/bf00959555 | ||
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Реферат:
The Ni(PPh3)n-Et3Al2Al3 catalytic system was found to be most effective for the dimerization of ethylene and propylene when the ligands Bu3PO and (BuO)2-PNEt2 were used in the Ni complex. For propylene dimerization in the liquid phase, the yield was 54 kmole/mole Ni-h at 40–55‡C. Using mathematical planning methods for the experiments the optimum conditions range for the formation of hexanes was found, in which selectivity for dimerization reached 85–96% at 80–90% conversion.
Библиографическая ссылка:
Furman D.B.
, Kudryashev A.V.
, Ivanov A.O.
, Pogorelov A.G.
, Yanchevskaya T.V.
, Bragin O.V.
Metal complexes in catalytic conversion of olefins. 3. Catalytic dimerization of ethylene and propylene by Ni(PPh3)n-Et3Al2Cl3 System
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1990. V.39. N3. P.444-447. DOI: 10.1007/bf00959555 РИНЦ OpenAlex
Metal complexes in catalytic conversion of olefins. 3. Catalytic dimerization of ethylene and propylene by Ni(PPh3)n-Et3Al2Cl3 System
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1990. V.39. N3. P.444-447. DOI: 10.1007/bf00959555 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 16 февр. 1989 г. |
Идентификаторы БД:
| РИНЦ: | 30833472 |
| OpenAlex: | W2055279480 |
Цитирование в БД:
| БД | Цитирований |
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| OpenAlex | 1 |