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Oxidation of unsaturated linear and cyclic hydrocarbons by molecular oxygen catalyzed by complexes of transition metals Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444
Вых. Данные Год: 1987, Том: 36, Номер: 1, Страницы: 131-136 Страниц : 6 DOI: 10.1007/bf00953862
Авторы Dzhemileva G.A. 1 , Odinokov V.N. 1 , Dzhemilev U.M. 1
Организации
1 Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, UFa,
Реферат: The catalytic system of PdCl2-CuCl permits the selective oxidation by oxygen in the THF solution of mono-, bi-, and tricyclic olefins, as well as 1,4E,9-decatriene, to high yields of carbonyl compounds. The Z double bond in the cyclic olefins possesses significantly less activity than the E-isomer in the oxidation by oxygen. The PdCl2-CuCl system in combination with H2O2, NiO2, KMnO4, NaOCl, or the oxides of silver and manganese can be utilized as an effective reagent for the selective oxidation of linear polyenes to carbonyl compounds.
Библиографическая ссылка: Dzhemileva G.A. , Odinokov V.N. , Dzhemilev U.M.
Oxidation of unsaturated linear and cyclic hydrocarbons by molecular oxygen catalyzed by complexes of transition metals
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1987. V.36. N1. P.131-136. DOI: 10.1007/bf00953862 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 11 апр. 1985 г.
Идентификаторы БД:
РИНЦ: 30904696
OpenAlex: W1994656076
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БД Цитирований
OpenAlex 1
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