Mechanism of the oxidation of methylbenzenes by Pd(II) Научная публикация
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Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444 |
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| Вых. Данные | Год: 1986, Том: 35, Номер: 6, Страницы: 1227-1232 Страниц : 6 DOI: 10.1007/bf00956603 | ||
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Реферат:
The oxidation of methylbenzenes (toluene, p-xylene, mesitylene, durene) by palladium- (II) to diarylmethanes in CF3COOH proceeds according to a mechanism of one-electron transfer. In addition, there is an oxidation of arenes to diaryls according to the well-known two-electron mechanism, including electrophilic substitution in the ring of the arene.
The contribution of the one-electron mechanism increases with decreasing ionization potential of the arene and with increasing acidity of the medium.
Complexes of palladium(I) (probably dimers) are intermediates of the one-electron oxidation of methylbenzenes to diarylmethanes.
Библиографическая ссылка:
Kozhevnikov I.V.
, Kim V.I.
, Sidel'nikov V.N.
Mechanism of the oxidation of methylbenzenes by Pd(II)
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1986. V.35. N6. P.1227-1232. DOI: 10.1007/bf00956603 РИНЦ OpenAlex
Mechanism of the oxidation of methylbenzenes by Pd(II)
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1986. V.35. N6. P.1227-1232. DOI: 10.1007/bf00956603 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 7 дек. 1984 г. |
Идентификаторы БД:
| РИНЦ: | 30904680 |
| OpenAlex: | W2018161834 |
Цитирование в БД:
| БД | Цитирований |
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| OpenAlex | 1 |