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Influence of water vapor on the dehydrogenation of ethylbenzene in the presence of various hydrogen acceptors Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444
Вых. Данные Год: 1987, Том: 36, Номер: 4, Страницы: 678-681 Страниц : 4 DOI: 10.1007/bf00962296
Авторы Belomestnykh I.P. 1,2 , Skrigan E.A. 1,2 , Kozlov N.S. 1,2 , Isagulyants G.V. 1,2 , Shakhnovich G.V. 1,2 , Volkov R.N. 1,2 , Rozhdestvenskaya N.N. 1,2 , Panova V.P. 1,2
Организации
1 Institute of Physical Organic Chemistry, Academy of Sciences of the Belorussian SSR, Minsk
2 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
Реферат: Water vapor influences the activity and selectivity of a vanadium-magnesium catalyst during the dehydrogenation of ethylbenzene in the presence of hydrogen acceptors, viz., oxygen, nitrobenzene, and sulfur dioxide, reducing the formation of carbon on the surface of the catalyst and promoting elongation of the operation of the catalyst without regeneration. Water vapor provides for the formation of the optimally active catalyst surface, which contains vanadium ions in high oxidation states with octahedral coordination.
Библиографическая ссылка: Belomestnykh I.P. , Skrigan E.A. , Kozlov N.S. , Isagulyants G.V. , Shakhnovich G.V. , Volkov R.N. , Rozhdestvenskaya N.N. , Panova V.P.
Influence of water vapor on the dehydrogenation of ethylbenzene in the presence of various hydrogen acceptors
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1987. V.36. N4. P.678-681. DOI: 10.1007/bf00962296 РИНЦ OpenAlex
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Поступила в редакцию: 2 авг. 1985 г.
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РИНЦ: 28442445
OpenAlex: W2090780711
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