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Substitution reactions involving organoaluminum compounds. No. 6. Synthesis of conjugated diallenes and allenynes from propargyl diacetates Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444
Вых. Данные Год: 1987, Том: 36, Номер: 6, Страницы: 1227-1233 Страниц : 7 DOI: 10.1007/bf00956668
Авторы Tolstikov G.A. 1 , Romanova T.Yu. 1 , Muslukhov R.R. 1 , Kuchin A.V. 1
Организации
1 Institute of Chemistry, Bashkir Affiliate, Academy of Sciences of the USSR, Ufa
Реферат: The reaction of tertiary and secondary propargylic diacetates derived from diacetylenic glycols with triethyl,- and triisobutylaluminum, catalyzed by FeCl3, is a suitable method for the preparative synthesis of conjugated diallenes. We have developed a method for the synthesis of oxygen-containing alienes and allenynes from mono- and diacetylenic glycol diacetates, based on the greater reactivity of tertiary propargyl acetate groups relative to primary ones with respect to trialkylalanes.
Библиографическая ссылка: Tolstikov G.A. , Romanova T.Y. , Muslukhov R.R. , Kuchin A.V.
Substitution reactions involving organoaluminum compounds. No. 6. Synthesis of conjugated diallenes and allenynes from propargyl diacetates
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1987. V.36. N6. P.1227-1233. DOI: 10.1007/bf00956668 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 9 июл. 1985 г.
Идентификаторы БД:
РИНЦ: 30857435
OpenAlex: W2051972291
Альметрики: