Rate of formation of free radicals in decomposition of hydroperoxides catalyzed by cobalt and copper acetylacetonates

Rate of formation of free radicals in decomposition of hydroperoxides catalyzed by cobalt and copper acetylacetonates Научная публикация

Журнал

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444

Вых. Данные

Год: 1987, Том: 36, Номер: 2, Страницы: 246-251 Страниц : 6 DOI: 10.1007/bf00959356

Авторы

Nikitin A.V. ¹ , Kasparov V.V. ¹ , Rubailo V.L. ¹ , Gagarina A.B. ¹

Организации

1	Institute of Chemical physics, Academy of Sciences of the USSR, Moscow,

The method of quasistationary concentrations in the kinetic description of free radical decomposition of azobisisobutyronitrile in the presence of 1,2-bis-(4,4′-dimethylaminophenyl)-1,2-diphthaloylethane was experimentally substantiated.2. The catalytic activity of Co(III) acetylacetonate increases during decomposition of tert-butyl hydroperoxide, and the catalyst reacts with the tert-butylperoxyl radicals.3. The reaction of copper (II) acetylacetonate with the free radicals formed during catalytic decomposition of cyclohexenyl peroxide is accompanied by the disappearance of the EPR signal of the copper ions.

Nikitin A.V. , Kasparov V.V. , Rubailo V.L. , Gagarina A.B.
Rate of formation of free radicals in decomposition of hydroperoxides catalyzed by cobalt and copper acetylacetonates
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1987. V.36. N2. P.246-251. DOI: 10.1007/bf00959356 РИНЦ OpenAlex

Поступила в редакцию:

17 июн. 19 г.

РИНЦ:	30857425
OpenAlex:	W2052242174