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Catalytic systems for processes of oxidative chlorination of hydrocarbons. Communication 5. Distribution of phases in copper chloride systems on ?-Al2O3 as determined by transmission electron microscopy and adsorption measurements Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230 , E-ISSN: 2376-8444
Вых. Данные Год: 1987, Том: 36, Номер: 6, Страницы: 1123-1127 Страниц : 5 DOI: 10.1007/bf00956644
Авторы Kurlyandakaya I.I. 1 , Dashevskii M.I. 1 , Solomonik I.G. 1 , Kudryavtseva T.F. 1 , Yakerson V.I. 2
Организации
1 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
2 State Scientific-Research and Design Institute of the Chlorine Industry, Moscow
Реферат: By means of electron microscopy and an investigation of adsorption, involving x-ray diffraction and DTA, the observed morphological structures have been characterized in the catalytic systems copper(II) chloride-α-aluminum oxide and copper (II) chloride-potassium chloride-α-aluminum oxide, When the catalytic, systems are heat-treated, the salt clusters acquire mobility as a consequence of the formation of fusible compositions or surface migration of salt phases in a premelting state. When this occurs, changes are observed in the structure and surface area of the salt clusters.
Библиографическая ссылка: Kurlyandakaya I.I. , Dashevskii M.I. , Solomonik I.G. , Kudryavtseva T.F. , Yakerson V.I.
Catalytic systems for processes of oxidative chlorination of hydrocarbons. Communication 5. Distribution of phases in copper chloride systems on ?-Al2O3 as determined by transmission electron microscopy and adsorption measurements
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1987. V.36. N6. P.1123-1127. DOI: 10.1007/bf00956644 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 5 сент. 1985 г.
Идентификаторы БД:
РИНЦ: 30836202
OpenAlex: W2075978035
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