Total oxidation of n-pentane, cyclohexane and their mixtures on the Cu-containing ZSM-5 zeolites

Total oxidation of n-pentane, cyclohexane and their mixtures on the Cu-containing ZSM-5 zeolites Тезисы доклада

Конференция

13th International Zeolite Conference
08-13 июн. 2001 , Montpellier

Журнал

Studies in Surface Science and Catalysis
ISSN: 0167-2991

Вых. Данные

Год: 2001, Том: 135, Номер статьи : 30-P-09, Страниц : 1 DOI: 10.1016/s0167-2991(01)81730-4

Авторы

Botavina M.A. , Nekrasov N.V. , Kiperman S.L.

Организации

1	N.D. Zelinsky Institute of Organic Chemistry RAS

This chapter presents the study of the kinetics of the total oxidation of n-pentane (n-C5H12), cyclohexane (C6H12), and their mixtures on copper (Cu)-containing ZSM-5 to analyze the possible effects of the critical size of reactant molecule on these processes. Oxidation of n-C5H12 seems to proceed in kinetic region, whereas C6H12 conversion is affected by intracrystalline diffusion of reactants. This conclusion is in a good accordance with hindrances for the mobility of investigated molecules. The oxidation of normal pentane takes place on all catalysts surface and its rate does not change in the presence of cyclohexane because of its low diffusivity while cyclohexane conversion decreases significantly in the presence of normal pentane.

Botavina M.A. , Nekrasov N.V. , Kiperman S.L.
Total oxidation of n-pentane, cyclohexane and their mixtures on the Cu-containing ZSM-5 zeolites
Studies in Surface Science and Catalysis. 2001. V.135. 30-P-09 :1-1. DOI: 10.1016/s0167-2991(01)81730-4 Scopus CAPlusCA OpenAlex

Scopus:	2-s2.0-84981744988
Chemical Abstracts:	2001:773372
Chemical Abstracts (print):	136:73655
OpenAlex:	W1534407229

БД	Цитирований
Scopus	1