Oscillatory behavior during CO oxidation over Pd supported on glass fibers: experimental study and mathematical modeling

Oscillatory behavior during CO oxidation over Pd supported on glass fibers: experimental study and mathematical modeling Научная публикация

Журнал

Chemical Engineering Science
ISSN: 0009-2509

Вых. Данные

Год: 2000, Том: 55, Номер: 15, Страницы: 2827-2833 Страниц : 7 DOI: 10.1016/S0009-2509(99)00557-6

Авторы

Юранов Игорь Анатольевич ¹ , Киви-Минскер Л Л ¹ , Слинько Марина Михайловна ² , Куркина Елена Сергеевна ³ , Толстунова Е Д ² , Renken Albert K E ¹

Организации

1	Ecole Polytechnique Fédérale de Lausanne
2	Institute of Chemical Physics, Russian Academy of Sciences
3	Lomonosov Moscow State University

The oscillatory behavior during CO oxidation over Pd supported on glass fibers was studied in a recycle reactor. The properties of oscillations as a function of temperature and inlet CO concentration were investigated in detail. The peculiarity of the observed oscillations is their long period up to 6 h. Mathematical model considering oxidation–reduction processes of the Pd has been developed to describe the experimental results. The model accounts for the observed reaction rate dependence on the CO inlet concentration, the region of oscillations and the dependence of the oscillatory behavior upon temperature and CO inlet concentration.

Yuranov I. , Kiwi-Minsker L.L. , Slinko M.M. , Kurkina E.S. , Tolstunova E.D. , Renken A.
Oscillatory behavior during CO oxidation over Pd supported on glass fibers: experimental study and mathematical modeling
Chemical Engineering Science. 2000. V.55. N15. P.2827-2833. DOI: 10.1016/S0009-2509(99)00557-6 Scopus

Scopus:

2-s2.0-0034107005

БД	Цитирований
Scopus	26