The influence of the magnetic field as a tool for investigation of the mechanism of reations of triethylgermyl radicals Научная публикация
| Журнал |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
|---|---|
| Вых. Данные | Год: 1983, Том: 256, Номер: 1, Страницы: 31-36 Страниц : 6 DOI: 10.1016/S0022-328X(00)99293-3 |
| Авторы |
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| Организации |
Реферат:
The influence of the external magnetic field on the product yield in the reaction of Et3GeM (where M=Na, K) withy benzyl chloride was investigated. A mechanism for magnetic effects in this reaction is proposed. To verify the mechanism proposed, theoretical calculations of the recombination probability of triethylgermyl and benzyl singlet radical pairs were carried out. It is proposed that associated state of the organometallic compound in solution affects the cage and the magnetic effects.
Библиографическая ссылка:
Taraban M.B.
, Leshina T.V.
, Salikhov K.M.
, Sagdeev R.Z.
, Molin Y.
, Margorskaya O.I.
, Vyazankin N.S.
The influence of the magnetic field as a tool for investigation of the mechanism of reations of triethylgermyl radicals
Journal of Organometallic Chemistry. 1983. V.256. N1. P.31-36. DOI: 10.1016/S0022-328X(00)99293-3CAPlusCA
The influence of the magnetic field as a tool for investigation of the mechanism of reations of triethylgermyl radicals
Journal of Organometallic Chemistry. 1983. V.256. N1. P.31-36. DOI: 10.1016/S0022-328X(00)99293-3CAPlusCA
Идентификаторы БД:
| Chemical Abstracts: | 1984:68419 |
| Chemical Abstracts (print): | 100:68419 |