An investigation of the mechanism of the reation of allyltriethylstannane with bromotrichloromethane by radiofrequency probing and chemically induced dynamic nuclear polarization (CIDNP)

An investigation of the mechanism of the reation of allyltriethylstannane with bromotrichloromethane by radiofrequency probing and chemically induced dynamic nuclear polarization (CIDNP) Научная публикация

Журнал	Journal of Organometallic Chemistry ISSN: 0022-328X
Вых. Данные	Год: 1983, Том: 259, Номер: 3, Страницы: 295-300 Страниц : 6 DOI: 10.1016/0022-328X(83)87179-4
Авторы	Лешина Татьяна Викторовна , Сагдеев Ренад Зиннурович , Поляков Н Э , Тарабан М Б , Валяев В И , Рахлин Владимир Исаакович , Мирсков Р Г , Khangazheev S.Kh. , Воронков М Г
Организации

The methods of radiofrequency probing (RFP) and chemically induced dynamic nuclear polarization (CIDNP) have been used to study the mechanism of the reaction of allyltriethylstannane with bromotrichloromethane. The CIDNP effects which have been detected prove the presence of radical stages in this reaction. An assumption has been made about a possible radical pathway for the β-decomposition of elementorganic compounds.

Лешина Т.В. , Сагдеев Р.З. , Поляков Н.Э. , Тарабан М.Б. , Валяев В.И. , Рахлин В.И. , Мирсков Р.Г. , Khangazheev S.K. , Воронков М.Г.
An investigation of the mechanism of the reation of allyltriethylstannane with bromotrichloromethane by radiofrequency probing and chemically induced dynamic nuclear polarization (CIDNP)
Journal of Organometallic Chemistry. 1983. Т.259. №3. С.295-300. DOI: 10.1016/0022-328X(83)87179-4CAPlusCA

Chemical Abstracts:	1984:174963
Chemical Abstracts (print):	100:174963