Photoinitiated reactions of allyltriorgano-silanes and -germanes with polyhaloidalkanes. Study of the mechanisms of the reactions by means of the 1H CIDNP method

Photoinitiated reactions of allyltriorgano-silanes and -germanes with polyhaloidalkanes. Study of the mechanisms of the reactions by means of the 1H CIDNP method Научная публикация

Журнал	Journal of Organometallic Chemistry ISSN: 0022-328X
Вых. Данные	Год: 1986, Том: 299, Номер: 3, Страницы: 271-277 Страниц : 7 DOI: 10.1016/0022-328X(86)84001-3
Авторы	Лешина Татьяна Викторовна , Валяев В И , Тарабан М Б , Марьясова В И , Рахлин Владимир Исаакович , Khangazheev S.Kh. , Мирсков Р Г , Воронков М Г
Организации

The radical stages in the photolysis reactions of various allyltriorgano-silanes and -germanes (R3MCH2CHCH2; M = Si, Ge) with polyhaloidalkanes have been studied using the 1H CIDNP method. It has been shown that the mechanism of the photochemical reaction for M = Sn, Ge is different from the case when M = Sn. Some rather stable R3MCH2CH(Hal)CH2R′ (M = Si, Ge) derivatives were isolated and characterized.

Leshina T.V. , Valyaev V.I. , Taraban M.B. , Maryasova V.I. , Rakhlin V.I. , Khangazheev S.K. , Mirskov R.G. , Voronkov M.G.
Photoinitiated reactions of allyltriorgano-silanes and -germanes with polyhaloidalkanes. Study of the mechanisms of the reactions by means of the 1H CIDNP method
Journal of Organometallic Chemistry. 1986. V.299. N3. P.271-277. DOI: 10.1016/0022-328X(86)84001-3CAPlusCA

Chemical Abstracts:	1986:609063
Chemical Abstracts (print):	105:209063