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Interaction between nitrogen monoxide and carbon monoxide on the surface of CuCo2O4 spinel Научная публикация

Журнал Applied Catalysis
ISSN: 0166-9834
Вых. Данные Год: 1986, Том: 24, Номер: 1-2, Страницы: 37-51 Страниц : 15 DOI: 10.1016/S0166-9834(00)81256-7
Авторы Panaiotov D. , Matyshak V. , Sklyarov A. , Vlasenko A. , Mekhandzhiev D.
Организации
1 Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences
2 Institute of Chemical Physics, Russian Academy of Sciences
Реферат: The interaction between NO and CO on the surface of CuCo2O4 spinel catalyst was investigated at 293-700 K. The formation of (CO.NO)x complexes of a carbonate, nitro or nitrate type seem to determine the low-temperature interaction mechanism. At temperatures >470 K the catalyst at first consumed CO after which neutralization of NO began. A mechanism is proposed based on the interaction between NO from the gas phase and pre-adsorbed CO. No formation of isocyanate complexes was observed irresp. of the high CO:NO ratio (5:1).
Библиографическая ссылка: Panaiotov D. , Matyshak V. , Sklyarov A. , Vlasenko A. , Mekhandzhiev D.
Interaction between nitrogen monoxide and carbon monoxide on the surface of CuCo2O4 spinel
Applied Catalysis. 1986. V.24. N1-2. P.37-51. DOI: 10.1016/S0166-9834(00)81256-7CAPlusCA
Идентификаторы БД:
Chemical Abstracts: 1986:485764
Chemical Abstracts (print): 105:85764
Альметрики: