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Effect of the Textural Characteristics of the Support on the Activity of Chromium Oxide Catalysts in the Propane Dehydrogenation Reaction in the Presence of CO2 Научная публикация

Журнал Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Вых. Данные Год: 2025, Том: 99, Номер: 6, Страницы: 1262-1269 Страниц : 8 DOI: 10.1134/s0036024425700608
Авторы Tedeeva M.A. 1 , Mashkin M.Yu. 1 , Andresyuk A.A. 1 , Pribytkov P.V. 1 , Medvedev A.A. 2 , Tkachenko O.P. 2 , Kapustin G.I. 2 , Dunaev S.F. 1 , Kustov A.L. 1
Организации
1 Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia
2 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
Реферат: Two sets of CrOx–SBA-15 catalysts are synthesized by the different methods, namely, coprecipitation with a support and incipient wetness impregnation, while varying the chromium content in the catalyst in a range of 3–7 wt %. The synthesized materials are studied by the nitrogen adsorption, UV–Vis diffuse reflectance spectroscopy, and diffuse reflectance infrared Fourier transform spectroscopy methods using CD3CN as a probe molecule. In the presence of a 3 wt % Cr–SiO2 catalyst synthesized by coprecipitation, a propylene selectivity of 78% at a propane conversion of 14% at 600°C is achieved.
Библиографическая ссылка: Tedeeva M.A. , Mashkin M.Y. , Andresyuk A.A. , Pribytkov P.V. , Medvedev A.A. , Tkachenko O.P. , Kapustin G.I. , Dunaev S.F. , Kustov A.L.
Effect of the Textural Characteristics of the Support on the Activity of Chromium Oxide Catalysts in the Propane Dehydrogenation Reaction in the Presence of CO2
Russian Journal of Physical Chemistry A. 2025. V.99. N6. P.1262-1269. DOI: 10.1134/s0036024425700608 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 10 дек. 2024 г.
Принята к публикации: 31 янв. 2025 г.
Опубликована online: 15 июн. 2025 г.
Идентификаторы БД:
≡ РИНЦ: 82558530
  • Добавил Альперина Г.Л. 16 февр. 2026 г.
≡ OpenAlex: W4411313413
  • Добавил Альперина Г.Л. 16 февр. 2026 г.
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