Реферат: The oxidation of toluene, benzaldehyde, and NH3, and the oxidizing ammonolysis of toluene on a V2O5-Cr2O3- Al2O3 catalyst have been investigated. The formation of benzonitrile from toluene in the course of oxidizing ammonolysis does not involve any oxygen- containing intermediates (Benzaldehyde and benzoic acid). The fact that ammonia-treated catalyst and air- treated catalyst display the same activity in the course of ammonolysis indicates that treatment of the catalyst with ammonia leads o a loss of its toluene- oxidizing ability. The experimentsalso indicate that synthesis of benzonitrile involves no oxygen-containing intermediates. A new mechanism of formation of benzonitrile from toluene, NH3, and air, involving amine and amide intermediates, is suggested.

Библиографическая ссылка: Seeboth H. , Buettner W. , Rieche A.
Mechanism of the catalytic formation of benzonitrile from toluene, ammonia, and air in the gas phase (oxidative ammonolysis)
Kinetics and Catalysis. 1969. V.10. N4. P.669-672. Scopus

Оригинальная версия: Зеебот Х. , Бютнер В. , Рихе А.
О механизме каталитического образования бензонитрила из толуола, NH3 и воздуха в газовой фазе (окислительный аммонолиз)
Кинетика и катализ. 1969. Т.10. №4. С.818-822. CAPlusCA

Даты:

Поступила в редакцию:

22 мая 1968 г.

Идентификаторы БД:

Scopus:

2-s2.0-0014535785