Kinetics and mechanism of the hydrobromination of C2H5OH by hydrogen bromide in aqueous HBr and H2SO4 solutions with HBr Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 1988, Том: 29, Номер: 1, Страницы: 70-76 Страниц : 7 | ||||
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Реферат:
The kinetic principles governing the formation of C2H5Br form ethanol and HBr have been studied in aqueous solutions in the absence and presence of sulfuric acid. The reaction has been found to be an equilibrium reaction, with the C2H5Br separated practically completely in the vapor phase. The equilibrium is established at the very beginning of the reaction, and the rate of formation of C2H5Br is determined by the HBr and ethanol concentrations and the acidity of the medium. Second order rate constants were measured for the formation of C2H5Br relative to the acidity of the medium, and corrected to a single standard state.
Библиографическая ссылка:
Vinnik M.I.
, Skakun S.A.
, Tribrat I.G.
Kinetics and mechanism of the hydrobromination of C2H5OH by hydrogen bromide in aqueous HBr and H2SO4 solutions with HBr
Kinetics and Catalysis. 1988. V.29. N1. P.70-76. WOS Scopus РИНЦ
Kinetics and mechanism of the hydrobromination of C2H5OH by hydrogen bromide in aqueous HBr and H2SO4 solutions with HBr
Kinetics and Catalysis. 1988. V.29. N1. P.70-76. WOS Scopus РИНЦ
Оригинальная версия:
Винник М.И.
, Скакун С.А.
, Трибрат И.Г.
Кинетика и механизм гидробромирования C2H5OH бромистым водородом в водных растворах HBr и H2SO4 с HBr
Кинетика и катализ. 1988. Т.29. №1. С.81-87. CAPlusCAРЖ ВИНИТИ
Кинетика и механизм гидробромирования C2H5OH бромистым водородом в водных растворах HBr и H2SO4 с HBr
Кинетика и катализ. 1988. Т.29. №1. С.81-87. CAPlusCAРЖ ВИНИТИ
Даты:
| Поступила в редакцию: | 13 февр. 1987 г. |
Идентификаторы БД:
| Web of science: | WOS:A1988Q452200012 |
| Scopus: | 2-s2.0-0024045179 |
| РИНЦ: | 30954398 |