Kinetic patterns of oxidative chlorination of acetylene to monochloroacetylene and trans-1,2-dichloroethylene in aqueous solutions of copper (I) and (II) chlorides

Kinetic patterns of oxidative chlorination of acetylene to monochloroacetylene and trans-1,2-dichloroethylene in aqueous solutions of copper (I) and (II) chlorides Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1988, Том: 29, Номер: 5, Страницы: 898-903 Страниц : 6

Авторы

Shcheltsyn L.V. , Brailovskii S.M. , Murugova E.Y. , Temkin O.N.

Организации

1	MIREA - Russian Technological University

Kinetic equations for the synthesis of monochloroacetylene and trans-1,2-dichloroethylene in an aqueous solution of copper (I) and (II) chlorides containing NH4Cl, were obtained as functions of partial pressure of acetylene and Cu(I), Cu(II) and H3O+ concentrations. The activation energies of formation of monochloroacetylene and trans-1,2-dichloroethylene were determined. The reaction mechanisms are discussed.

Shcheltsyn L.V. , Brailovskii S.M. , Murugova E.Y. , Temkin O.N.
Kinetic patterns of oxidative chlorination of acetylene to monochloroacetylene and trans-1,2-dichloroethylene in aqueous solutions of copper (I) and (II) chlorides
Kinetics and Catalysis. 1988. V.29. N5. P.898-903. WOS Scopus РИНЦ

Щельцын Л.В. , Брайловский С.М. , Муругова Е.Ю. , Темкин О.Н.
Кинетические закономерности окислительного хлорирования ацетилена до монохлорацетилена и транс-1,2-дихлорэтилена в водных растворах хлоридов меди (I) и (II)
Кинетика и катализ. 1988. Т.29. №5. С.1044-1049. CAPlusCAРЖ ВИНИТИ

Поступила в редакцию:

7 июл. 1987 г.

Web of science:	WOS:A1988AC96500003
Scopus:	2-s2.0-0024630922
РИНЦ:	31073805