Реферат: The general principles of the calorimetric studies of nonequilibrium gas-solid systems and applications various of methods usually referred to as differential scanning calorimetry to heterogeneous catalysis are considered. In situ differential scanning calorimetry is used to investigate the dynamic thermochemical state of the systems. Along with its traditional application (phase transitions and chemical reactions in catalysts and their solid precursors, the qualitative and quantitative analysis of the phase composition of the samples, and the characterization of energetic nonuniformity of solid surfaces), the differential scanning calorimetry may also be used to study the mechanisms of complex catalytic processes: the construction of thermochemical properties vs. reactivity diagrams, the discrimination of the mechanisms of the heterogeneous activation of gaseous molecules, the evolution of active surface sites and states of solid bulk, and the construction of kinetic models for complex heterogeneous-homogeneous processes.

Библиографическая ссылка: Sinev M.Y. , Bychkov V.Y.
High-temperature differential scanning in situ calorimetric study of the mechanism of catalytic processes
Kinetics and Catalysis. 1999. V.40. N6. P.819-835. WOS Scopus РИНЦ CAPlus OpenAlex

Оригинальная версия: Синев М.Ю. , Бычков В.Ю.
Высокотемпературная дифференциальная сканирующая калориметрия in situ в исследовании механизма каталитических процессов
Кинетика и катализ. 1999. Т.40. №6. С.906-925. РЖ ВИНИТИ

Даты:

Поступила в редакцию:	11 июн. 1999 г.
Опубликована в печати:	1 нояб. 1999 г.

Идентификаторы БД:

Web of science:	WOS:000084606000009
Scopus:	2-s2.0-0038144535
РИНЦ:	13307174
Chemical Abstracts:	2000:34071
OpenAlex:	W2513383372

Цитирование в БД:

БД	Цитирований
Web of science	13
Scopus	14
OpenAlex	9