Реферат: (7% Pd)/C catalysts have been prepared by the pyrolysis of untreated sawdust and sawdust washed with an acid to remove of Group I and II metal impurities, both impregnated with palladium nitrate. Studies by transmission electron microscopy, X-ray photoelectron spectroscopy, and temperature-programmed reduction have demonstrated that the dominant palladium species in the catalysts is 2-5 nm Pd-0 particles, there is no PdO on the surface, and the catalyst bulk contains small amounts of larger (10-20 nm) PdO particles. The catalysts are active in chlorobenzene hydrodechlorination in a fixed-bed flow reactor and ensure 100% conversion of the substrate into benzene in the temperature range from 250 to 350A degrees C. At lower temperatures (150-200A degrees C), the catalyst containing calcium is the most active and the sample subjected to reduction after pyrolysis shows the lowest activity.

Библиографическая ссылка: Lokteva E.S. , Golubina E.V. , Antonova M.V. , Klokov S.V. , Maslakov K.I. , Egorov A.V. , Likholobov V.A.
Chlorobenzene hydrodechlorination catalyst prepared via the pyrolysis of sawdust impregnated with palladium nitrate
Kinetics and Catalysis. 2015. V.56. N6. P.764-773. DOI: 10.1134/S0023158415060099 WOS Scopus РИНЦ CAPlus OpenAlex

Оригинальная версия: Локтева Е.С. , Голубина Е.В. , Антонова М.В. , Клоков С.В. , Маслаков К.И. , Егоров А.В. , Лихолобов В.А.
Катализатор гидродехлорирования хлорбензола, полученный пиролизом пропитанных нитратом палладия древесных опилок
Кинетика и катализ. 2015. Т.56. №6. С.753-762. DOI: 10.7868/S0453881115060106 РИНЦ РЖ ВИНИТИ OpenAlex

Даты:

Поступила в редакцию:	27 нояб. 2014 г.
Опубликована в печати:	1 нояб. 2015 г.

Идентификаторы БД:

Web of science:	WOS:000365450000008
Scopus:	2-s2.0-84948413861
РИНЦ:	24975490
Chemical Abstracts:	2015:1918988
OpenAlex:	W2207934020

Цитирование в БД:

БД	Цитирований
Web of science	11
Scopus	11
OpenAlex	16

Альметрики: