Heterogeneous Reaction of Dimethyl Sulfide with Iodine Oxide in a Temperature Range of 291-365 K Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2021, Том: 62, Номер: 2, Страницы: 245-254 Страниц : 10 DOI: 10.1134/S0023158421020063 | ||
| Авторы |
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| Организации |
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Реферат:
A reaction of the iodine oxide (IO) radical with dimethyl sulfide (DMS) in a temperature range of 291–365 K was studied using atomic iodine resonance fluorescence. It was found that this reaction was mainly heterogeneous under the experimental conditions, and the rate constant of the heterogeneous reaction was almost an order of magnitude higher than the rate constant of a homogeneous reaction. The temperature dependence of the rate constant of this reaction can be represented by the following expression: k(T) = 1.5 × 10–14 [±3 × 10–15 cm3 molecule–1 s–1] exp(7150[±800 J/mol]/RT). The conditions under which the heterogeneous reaction of DMS with the IO radical can play a noticeable role in the oxidation of DMS in the atmosphere are discussed.
Библиографическая ссылка:
Larin I.K.
, Belyakova T.I.
, Messineva N.A.
, Spassky A.I.
, Trofimova E.M.
Heterogeneous Reaction of Dimethyl Sulfide with Iodine Oxide in a Temperature Range of 291-365 K
Kinetics and Catalysis. 2021. V.62. N2. P.245-254. DOI: 10.1134/S0023158421020063 WOS Scopus РИНЦ CAPlus OpenAlex
Heterogeneous Reaction of Dimethyl Sulfide with Iodine Oxide in a Temperature Range of 291-365 K
Kinetics and Catalysis. 2021. V.62. N2. P.245-254. DOI: 10.1134/S0023158421020063 WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная версия:
Ларин И.К.
, Белякова Т.И.
, Мессинева Н.А.
, Спасский А.И.
, Трофимова Е.М.
Гетерогенная реакция диметилсульфида с оксидом йода в области температур 291–365 К
Кинетика и катализ. 2021. Т.62. №2. С.187-197. DOI: 10.31857/S0453881121020064 РИНЦ OpenAlex
Гетерогенная реакция диметилсульфида с оксидом йода в области температур 291–365 К
Кинетика и катализ. 2021. Т.62. №2. С.187-197. DOI: 10.31857/S0453881121020064 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 26 апр. 2020 г. |
| Принята к публикации: | 30 нояб. 2020 г. |
| Опубликована в печати: | 1 мар. 2021 г. |
| Опубликована online: | 16 апр. 2021 г. |
Идентификаторы БД:
| Web of science: | WOS:000640512300003 |
| Scopus: | 2-s2.0-85104354731 |
| РИНЦ: | 46767237 |
| Chemical Abstracts: | 2021:899263 |
| OpenAlex: | W3152509320 |