Partial Oxidation of Ethane in the Temperature Range 773-1023 K | Sciact

Partial Oxidation of Ethane in the Temperature Range 773-1023 K Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2021, Том: 62, Номер: 6, Страницы: 703-711 Страниц : 9 DOI: 10.1134/S0023158421060021

Авторы

Bryukov M.G. ¹ , Palankoeva A.S. ^1,2 , Belyaev A.A. ¹ , Arutyunov V.S. ^1,2,3

Организации

1	Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia
2	Faculty of Fundamental Physical and Chemical Engineering, Moscow State University, 119234, Moscow, Russia
3	Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

The results of an experimental study of the partial oxidation of ethane in the temperature range 773–1023 K and at pressures of 1 and 2 atm in a flow reactor with chromatographic analysis of the gas mixture were presented. Oxygen and nitrogen were used as an oxidizer and carrier gas, respectively. The excess fuel ratio was varied from 7.0 to 15.3. Numerical simulation with a detailed description of the complex kinetics of ethane oxidation was performed. The necessity of taking into account heterogeneous processes on the reactor surface under these conditions was shown and a method for this was proposed. When the detailed gas-phase mechanisms of ethane oxidation are complemented with stages describing heterogeneous processes on the surface of the quartz reactor, the results of numerical modeling are in good agreement with the experimental data.

Bryukov M.G. , Palankoeva A.S. , Belyaev A.A. , Arutyunov V.S.
Partial Oxidation of Ethane in the Temperature Range 773-1023 K
Kinetics and Catalysis. 2021. V.62. N6. P.703-711. DOI: 10.1134/S0023158421060021 WOS Scopus РИНЦ CAPlus OpenAlex

Брюков М.Г. , Паланкоева А.С. , Беляев А.А. , Арутюнов В.С.
Парциальное окисление этана в диапазоне температур 773–1023 K
Кинетика и катализ. 2021. Т.62. №6. С.666-677. DOI: 10.31857/S0453881121060022 РИНЦ OpenAlex

Поступила в редакцию:	20 апр. 2021 г.
Принята к публикации:	5 авг. 2021 г.
Опубликована в печати:	1 нояб. 2021 г.
Опубликована online:	11 янв. 2022 г.

Web of science:	WOS:000740995000002
Scopus:	2-s2.0-85122467483
РИНЦ:	47909125
Chemical Abstracts:	2022:76424
OpenAlex:	W4205106489

БД	Цитирований
Web of science	6
Scopus	7
OpenAlex	6