Features of Hydrolysis of Concentrated Aqueous Alkaline Solutions of NaBH4 on Co/TiO2 Catalyst

Features of Hydrolysis of Concentrated Aqueous Alkaline Solutions of NaBH4 on Co/TiO2 Catalyst Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2022, Том: 63, Номер: 5, Страницы: 585-592 Страниц : 8 DOI: 10.1134/S002315842205010X

Авторы

Shabunya S.I. , Minkina V.G. , Kalinin V.I.

Организации

1	Luikov Heat and Mass Transfer Institute, National Academy of Sciences of Belarus, 220072, Minsk, Belarus

Kinetic experiments were carried out on the hydrolysis of concentrated aqueous and aqueous alkaline solutions of NaBH4 with a Co/TiO2 catalyst. The experiments in the aqueous NaBH4 solutions were performed at molal concentrations of 0.25, 1, and 4 mol/kg. In the aqueous alkaline solutions with molal NaBH4 concentrations of 0.25 and 1 mol/kg, the molal NaOH concentrations were varied in the range 0.05–8 mol/kg. The activation energies in the aqueous solution and the aqueous alkaline solutions were found to be 64.3 and 53.6 kJ/mol, respectively. Features of the kinetic curves and the possible kinetic schemes were discussed.

Shabunya S.I. , Minkina V.G. , Kalinin V.I.
Features of Hydrolysis of Concentrated Aqueous Alkaline Solutions of NaBH4 on Co/TiO2 Catalyst
Kinetics and Catalysis. 2022. V.63. N5. P.585-592. DOI: 10.1134/S002315842205010X WOS Scopus РИНЦ CAPlus OpenAlex

Шабуня С.И. , Минкина В.Г. , Калинин В.И.
Особенности гидролиза концентрированных водно-щелочных растворов NaBH4 на катализаторе CO/TiO2
Кинетика и катализ. 2022. Т.63. №5. С.661-668. DOI: 10.31857/S0453881122050112 РИНЦ OpenAlex

Поступила в редакцию:	1 мар. 2022 г.
Принята к публикации:	14 апр. 2022 г.
Опубликована online:	23 сент. 2022 г.
Опубликована в печати:	1 окт. 2022 г.

Web of science:	WOS:000856975300014
Scopus:	2-s2.0-85138601132
РИНЦ:	59769671
Chemical Abstracts:	2022:2471919
OpenAlex:	W4297003603

БД	Цитирований
Web of science	1
Scopus	1
OpenAlex	1