Effect of Tail Gas Recirculation Mode on the Activity and Selectivity of the Сo/SiO2 Catalyst for Fischer‒Tropsch Synthesis Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2022, Том: 63, Номер: 6, Страницы: 765–772 Страниц : DOI: 10.1134/S0023158422060131 | ||||||
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Реферат:
The effect of the gas recirculation mode on the selectivity and deactivation rate of the Co-Al2O3/SiO2 catalyst of the Fischer‒Tropsch synthesis at high pressure (6 MPa) has been studied. The use of recirculation with a gas recycle ratio of up to 2.2 promotes the formation of C19+ hydrocarbons due to the readsorption of gaseous olefins and their involvement in chain propagation. The increased selectivity for C19+ paraffin leads to accelerated deactivation of the catalyst. An increase in the gas recycle ratio to 8 leads to increased selectivity for C5+ olefins and a lower yield of C19+ waxes due to the removal of C5+ olefin vapors from the reaction zone. The latter is associated with a decreased contribution of the readsorption of higher C5+ olefins to the elongation of the carbon chain. At high gas recycle ratios, CoO was reduced to the metal, which partially compensates for catalyst deactivation as a result of the blocking of the active sites of chain propagation by C19+ waxes.
Библиографическая ссылка:
Soromotin V.N.
, Yakovenko R.E.
, Krasnyakova T.V.
, Svetogorov R.D.
, Mitchenko S.A.
Effect of Tail Gas Recirculation Mode on the Activity and Selectivity of the Сo/SiO2 Catalyst for Fischer‒Tropsch Synthesis
Kinetics and Catalysis. 2022. V.63. N6. P.765–772. DOI: 10.1134/S0023158422060131 WOS Scopus РИНЦ CAPlus OpenAlex
Effect of Tail Gas Recirculation Mode on the Activity and Selectivity of the Сo/SiO2 Catalyst for Fischer‒Tropsch Synthesis
Kinetics and Catalysis. 2022. V.63. N6. P.765–772. DOI: 10.1134/S0023158422060131 WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная версия:
Соромотин В.Н.
, Яковенко Р.Е.
, Краснякова Т.В.
, Светогоров Р.Д.
, Митченко С.А.
Влияние циркуляции хвостовых газов на активность и селективность Сo/SiO2-катализатора синтеза Фишера‒Тропша
Кинетика и катализ. 2022. Т.63. №6. С.808-815. DOI: 10.31857/S0453881122060144 РИНЦ OpenAlex
Влияние циркуляции хвостовых газов на активность и селективность Сo/SiO2-катализатора синтеза Фишера‒Тропша
Кинетика и катализ. 2022. Т.63. №6. С.808-815. DOI: 10.31857/S0453881122060144 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 10 июл. 2022 г. |
| Принята к публикации: | 21 июл. 2022 г. |
| Опубликована online: | 6 мар. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:000944025100015 |
| Scopus: | 2-s2.0-85149906281 |
| РИНЦ: | 59512177 |
| Chemical Abstracts: | 2023:464334 |
| OpenAlex: | W4323339402 |