Discrimination between the Homogeneous and Heterogeneous Mechanisms of Catalysis in the Copper- and Ligand-Free Sonogashira Reaction Using Phase Trajectory Analysis Научная публикация
| Конференция |
Catalysis: from Science to Industry : VII International School-Conference for Young Scientists 11-15 окт. 2022 , Томск |
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| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2023, Том: 64, Номер: 4, Страницы: 431–438 Страниц : DOI: 10.1134/S0023158423040055 | ||
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Реферат:
The paper presents the results of a comparative study of the differential selectivity of the copper- and ligand-free Sonogashira reaction under so-called artificial multiroutness aimed at distinguishing between homogeneous and heterogeneous catalysis mechanisms. The use of different amounts of soluble and insoluble heterogeneous palladium catalyst precursors resulted in the same values of the differential reaction selectivity for competing aryl iodides, competing arylacetylenes, and their conversion products. The observed patterns are consistent with the occurrence of the Sonogashira reaction in solution through a homogeneous catalysis mechanism, in particular, in the presence of insoluble heterogeneous catalyst precursors.
Библиографическая ссылка:
Larina E.V.
, Kurokhtina A.A.
, Lagoda N.A.
, Grigoryeva T.A.
, Schmidt A.F.
Discrimination between the Homogeneous and Heterogeneous Mechanisms of Catalysis in the Copper- and Ligand-Free Sonogashira Reaction Using Phase Trajectory Analysis
Kinetics and Catalysis. 2023. V.64. N4. P.431–438. DOI: 10.1134/S0023158423040055 WOS Scopus РИНЦ CAPlusCA OpenAlex
Discrimination between the Homogeneous and Heterogeneous Mechanisms of Catalysis in the Copper- and Ligand-Free Sonogashira Reaction Using Phase Trajectory Analysis
Kinetics and Catalysis. 2023. V.64. N4. P.431–438. DOI: 10.1134/S0023158423040055 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная версия:
Ларина Е.В.
, Курохтина А.А.
, Лагода Н.А.
, Григорьева Т.А.
, Шмидт А.Ф.
Различение гомогенного и гетерогенного механизмов катализа “безмедной” “безлигандной” реакции Соногаширы методом анализа фазовых траекторий
Кинетика и катализ. 2023. Т.64. №4. С.428-436. DOI: 10.31857/S0453881123040068 РИНЦ OpenAlex
Различение гомогенного и гетерогенного механизмов катализа “безмедной” “безлигандной” реакции Соногаширы методом анализа фазовых траекторий
Кинетика и катализ. 2023. Т.64. №4. С.428-436. DOI: 10.31857/S0453881123040068 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 14 нояб. 2022 г. |
| Опубликована в печати: | 23 янв. 2023 г. |
| Принята к публикации: | 9 мар. 2023 г. |
| Опубликована online: | 23 июл. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:001034791000008 |
| Scopus: | 2-s2.0-85165553849 |
| РИНЦ: | 62349309 |
| Chemical Abstracts: | 2023:1546932 |
| Chemical Abstracts (print): | 183:349994 |
| OpenAlex: | W4385163599 |