Kinetics of the Oxyethylation of Alcohols with Consideration of the Effect of Association: Kinetic Aspects of Association

Kinetics of the Oxyethylation of Alcohols with Consideration of the Effect of Association: Kinetic Aspects of Association Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2023, Том: 64, Номер: 6, Страницы: 741–749 Страниц : DOI: 10.1134/S0023158423060162

Авторы

Stul’ B.Ya.

Организации

1	OOO NII Sintez, Moscow, 115088 Russia

It was supposed that, in the reaction of oxyethylation of alcohols, the kinetically independent unit is not a monomeric alcohol molecule, but a linear chain alcohol associate consisting of an average of n alcohol molecules, and that the reaction rate is of the first order not in the total concentration of all alcohol species, but in the concentration of these associates. The kinetic aspects of this phenomenon were considered. It was assumed that reactions of the first order in the concentration of an associated component, which are widespread in liquid-phase chemical kinetics, occur as a result of the release of the reaction product from the associate.

Stul’ B.Y.
Kinetics of the Oxyethylation of Alcohols with Consideration of the Effect of Association: Kinetic Aspects of Association
Kinetics and Catalysis. 2023. V.64. N6. P.741–749. DOI: 10.1134/S0023158423060162 WOS Scopus РИНЦ CAPlusCA OpenAlex

Стуль Б.Я.
Кинетика реакции оксиэтилирования спиртов с учетом влияния ассоциации. Кинетические аспекты ассоциации
Кинетика и катализ. 2023. Т.64. №6. С.710-719. DOI: 10.31857/S0453881123060187 РИНЦ OpenAlex

Поступила в редакцию:	21 дек. 2022 г.
Принята к публикации:	17 апр. 2023 г.
Опубликована online:	12 дек. 2023 г.

Web of science:	WOS:001122621800012
Scopus:	2-s2.0-85179699857
РИНЦ:	64452452
Chemical Abstracts:	2023:2603187
Chemical Abstracts (print):	185:336639
OpenAlex:	W4389625758