Kinetic Laws of Oxidation of para-tert-Butylcumene in the Presence of N-Hydroxyphthalimide Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2023, Том: 64, Номер: 6, Страницы: 750–758 Страниц : DOI: 10.1134/S002315842306006X | ||||
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Реферат:
The kinetics of the oxidation of para-tert-butylcumene to hydroperoxide by molecular oxygen in the presence of N-hydroxyphthalimide was studied. By analyzing the laws of the formation of hydroperoxide and byproducts, a mathematical model of the process was constructed, which adequately describes the changes in the concentrations of the main components of the reaction over time. The main role of N-hydroxyphthalimide is to convert peroxide radicals into the corresponding hydroperoxides, thereby reducing the yield of byproducts by decreasing the quadratic chain termination rate. Moreover, the formed N-hydroxyphthalimide radicals increase the rate of hydrocarbon oxidation. Thus, the use of N-hydroxyphthalimide in hydrocarbon oxidation processes results in an increase in the rate and selectivity of hydroperoxide formation.
Библиографическая ссылка:
Frolov A.S.
, Kurganova E.A.
, Sapunov V.N.
, Kozlovskii R.A.
, Koshel’ G.N.
, Yarkina E.M.
Kinetic Laws of Oxidation of para-tert-Butylcumene in the Presence of N-Hydroxyphthalimide
Kinetics and Catalysis. 2023. V.64. N6. P.750–758. DOI: 10.1134/S002315842306006X WOS Scopus РИНЦ CAPlusCA OpenAlex
Kinetic Laws of Oxidation of para-tert-Butylcumene in the Presence of N-Hydroxyphthalimide
Kinetics and Catalysis. 2023. V.64. N6. P.750–758. DOI: 10.1134/S002315842306006X WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная версия:
Фролов А.С.
, Курганова Е.А.
, Сапунов В.Н.
, Козловский Р.А.
, Кошель Г.Н.
, Яркина Е.М.
Кинетические закономерности процесса окисления пара-трет-бутилкумола в присутствии N-гидроксифталимида
Кинетика и катализ. 2023. Т.64. №6. С.720-729. DOI: 10.31857/S0453881123060072 РИНЦ OpenAlex
Кинетические закономерности процесса окисления пара-трет-бутилкумола в присутствии N-гидроксифталимида
Кинетика и катализ. 2023. Т.64. №6. С.720-729. DOI: 10.31857/S0453881123060072 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 8 февр. 2023 г. |
| Принята к публикации: | 15 июн. 2023 г. |
| Опубликована online: | 12 дек. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:001122621800006 |
| Scopus: | 2-s2.0-85179683335 |
| РИНЦ: | 64673185 |
| Chemical Abstracts: | 2023:2603178 |
| Chemical Abstracts (print): | 185:361850 |
| OpenAlex: | W4389616648 |