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Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2023, Том: 64, Номер: 6, Страницы: 862–871 Страниц : DOI: 10.1134/S0023158423060034
Авторы Bokarev D.A. 1 , Paramoshin I.V. 1 , Rassolov A.V. 1 , Kanaev S.A. 1 , Bragina G.O. 1 , Stakheev A.Yu. 1
Организации
1 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
Реферат: The characteristics of Mn catalysts supported on different carriers (SiO2 and BEA zeolite) in the processes of ozone decomposition and ozone-catalytic oxidation (OZCO) of volatile organic compounds (VOCs) were studied using n-butane as an example. The parent SiO2 was inactive in the test reactions, and the characteristics of Mn/SiO2 were determined by the catalytic properties of the supported MnOx oxide. In contrast to SiO2, BEA zeolite demonstrated significant catalytic activity, although at a temperature 50°C higher than that for Mn/BEA. The data obtained allowed us to conclude that the catalytic characteristics of Mn/BEA at 30–100°C were also determined by the Mn component of the catalyst. At higher temperatures, the catalytic properties of BEA significantly affected the course of the OZCO process. The zeolite carrier improved hydrocarbon conversion at 100–200°C and decreased the amount of ozone required for the OZCO process over Mn/BEA.
Библиографическая ссылка: Bokarev D.A. , Paramoshin I.V. , Rassolov A.V. , Kanaev S.A. , Bragina G.O. , Stakheev A.Y.
Support Effect on the Characteristics of Supported Manganese Catalysts in the O3-Catalytic Oxidation of Volatile Organic Compounds
Kinetics and Catalysis. 2023. V.64. N6. P.862–871. DOI: 10.1134/S0023158423060034 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная версия: Бокарев Д.А. , Парамошин И.В. , Рассолов А.В. , Канаев С.А. , Брагина Г.О. , Стахеев А.Ю.
Влияние носителя на характеристики mn-нанесенных катализаторов в O3-каталитическом окислении ЛОС
Кинетика и катализ. 2023. Т.64. №6. С.811-821. DOI: 10.31857/S0453881123060035 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 30 мая 2023 г.
Принята к публикации: 21 июл. 2023 г.
Идентификаторы БД:
Web of science: WOS:001122621800017
Scopus: 2-s2.0-85179733231
РИНЦ: 64176760
Chemical Abstracts: 2023:2603189
Chemical Abstracts (print): 185:248425
OpenAlex: W4389625426
Цитирование в БД:
БД Цитирований
Scopus 4
Web of science 2
OpenAlex 4
Альметрики: