Реферат: The properties of Pd/HZSM-5 and Pd–nP/HZSM-5 catalysts were studied in direct synthesis and side processes of decomposition and hydrogenation of H2O2 under mild conditions in ethanol and aqueous ethanol in the presence of an acid inhibitor. It was shown, using HRTEM, XRD, and ICP MS methods, that modification with phosphorus led to the formation of highly dispersed X-ray amorphous systems, which are structurally disordered solid solutions of phosphorus in palladium. The main factors governing the promoting effect of phosphorus on the yield of H2O2 are considered. It was established that the use of a zeolite support in the H form, along with the phosphorus and acid modifiers, inhibits the side process of H2O2 decomposition.

Библиографическая ссылка: Belykh L.B. , Skripov N.I. , Milenkaya E.A. , Kornaukhova T.A. , Sterenchuk T.P. , Stepanova Y.K. , Schmidt F.K.
Properties of Palladium-Phosphorus Catalysts Supported on HZSM-5 Zeolite in Direct Synthesis of Hydrogen Peroxide
Kinetics and Catalysis. 2024. V.65. N2. P.155-167. DOI: 10.1134/s0023158423601249 WOS Scopus РИНЦ CAPlus OpenAlex

Оригинальная версия: Белых Л.Б. , Скрипов Н.И. , Миленькая Е.А. , Корнаухова Т.А. , Стеренчук Т.П. , Степанова Ю.К. , Шмидт Ф.К.
Свойства палладий-фосфорных катализаторов, нанесенных на цеолит НZSM-5, в прямом синтезе пероксида водорода
Кинетика и катализ. 2024. Т.65. №2. С.173-187. DOI: 10.31857/s0453881124020067 РИНЦ OpenAlex

Даты:

Поступила в редакцию:	10 окт. 2023 г.
Принята к публикации:	20 нояб. 2023 г.
Опубликована online:	9 мая 2024 г.

Идентификаторы БД:

Web of science:	WOS:001217617000010
Scopus:	2-s2.0-85192542625
РИНЦ:	67308031
Chemical Abstracts:	2024:1043468
OpenAlex:	W4396782005

Цитирование в БД:

БД	Цитирований
OpenAlex	2
Scopus	2

Альметрики: