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Catalytic systems based on carbon fiber materials for the low-temperature oxidation of carbon monoxide Научная публикация

Журнал Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Вых. Данные Год: 2009, Том: 1, Номер: 4, Страницы: 348-354 Страниц : 7 DOI: 10.1134/s2070050409040102
Авторы Radkevich V.Z. 1 , Sen’ko T.L. 1 , Khaminets S.G. 1 , Wilson K. 2 , Egiazarov Yu.G. 1
Организации
1 Institute of Physicoorganic Chemistry, Belarussian Academy of Sciences, Minsk, Belarus
2 Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
Реферат: New heterogenized catalytic systems for the low-temperature oxidation of CO were synthesized by supporting solutions of Pd, Cu, and Fe salts on carbon fibrous materials (carbopon and busofit). The carbon supports were studied by elemental analysis, SEM, TGA, and TPD. The effects of the nature of the support, the concentration and composition of the active component, and the conditions of preparation on the efficiency of the catalytic system were studied. It was ascertained that attenuation of hydrophilic properties of the support led to the decrease in system activity. The investigation of the catalysts by XPS showed that sample treatment in the reaction medium results in redistribution of the components of the active phase in the near-surface layer of the catalyst. The catalytic system based on carbon fibrous material carbopon prepared by supporting active components (Pd, Cu, and Fe salts) in three stages with intermediate activation in the reaction medium ensures 95% conversion of CO under respiratory conditions, and is promising for the design of the main element of breathing masks on its basis.
Библиографическая ссылка: Radkevich V.Z. , Sen’ko T.L. , Khaminets S.G. , Wilson K. , Egiazarov Y.G.
Catalytic systems based on carbon fiber materials for the low-temperature oxidation of carbon monoxide
Catalysis in Industry. 2009. V.1. N4. P.348-354. DOI: 10.1134/s2070050409040102 WOS OpenAlex
Оригинальная версия: Радкевич В.З. , Сенько Т.Л. , Хаминец С.Г. , Вильсон К. , Егиазаров Ю.Г.
Каталитические системы на основе углеродных волокнистых материалов для низкотемпературного окисления монооксида углерода
Катализ в промышленности. 2009. №5. С.43-50. РИНЦ CAPlusCAРЖ ВИНИТИ
Даты:
Опубликована в печати: 1 дек. 2009 г.
Опубликована online: 7 янв. 2010 г.
Идентификаторы БД:
Web of science: WOS:000433657400010
OpenAlex: W2017794625
Цитирование в БД:
БД Цитирований
OpenAlex 1
Web of science 1
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