Реферат: A Pt(1.5%)Sn(0.25%)/Al2O3 catalyst synthesized by the sequential impregnation of γ-alumina with aqueous solutions of hydroplatinic acid and tin chloride has been characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The kinetic laws governing methylcyclohexane dehydrogenation to toluene and hydrogen in a tubular flow reactor in the isothermal mode at atmospheric pressure have been studied, while varying the reactant concentrations, contact time, and temperature. An empirical mathematical model of kinetics, which includes three adsorption forms of a bifunctional active site, has been developed. The model adequately describes the test data for the forward and reverse reaction routes.

Библиографическая ссылка: Lozhkin A.D. , Iskhakova L.D. , Milovich F.O. , Katsman E.A. , Bruk L.G.
Kinetics of Hydrogen and Toluene Production from Methylcyclohexane in the Presence of a PtSn/Al2O3 Catalyst
Kinetics and Catalysis. 2024. V.65. N3. P.280-297. DOI: 10.1134/s0023158424601426 WOS Scopus РИНЦ CAPlusCA OpenAlex

Даты:

Поступила в редакцию:	15 дек. 2023 г.
Принята к публикации:	7 мар. 2024 г.
Опубликована online:	15 авг. 2024 г.

Идентификаторы БД:

Web of science:	WOS:001292130800001
Scopus:	2-s2.0-85201367043
РИНЦ:	68611526
Chemical Abstracts:	2024:1811875
Chemical Abstracts (print):	188:281064
OpenAlex:	W4401605979

Альметрики: