Реферат: The author considers the main patterns characteristic of the processes of hydrogen chloride oxidation (the Deacon reaction) and oxidative methane and ethane chlorination. It is shown that the most widely recognized and best studied catalysts of these processes are copper chloride systems that are based on different supports and contain alkali and rare-earth metal chlorides, which reduce the entrainment of an active phase from the surface of a catalyst with a simultaneous increase in its activity. The prospects for using ruthenium catalysts are also noted. The main kinetic and technological patterns of oxychlorination are considered. Conditions are described that allow the yield of target products (lower methane chlorides) to be increased in the oxychlorination of methane and vinyl chloride during the oxychlorination of ethane. Variants of reactor units for oxychlorination are proposed.

Библиографическая ссылка: Flid M.R.
The Oxidative Chlorination of Hydrocarbons I: The Deacon Reaction. The Oxidative Chlorination of Saturated C1 and C2 Hydrocarbons
Catalysis in Industry. 2024. V.16. N3. P.217–243. DOI: 10.1134/S2070050424700119 WOS Scopus РИНЦ OpenAlex

Оригинальная версия: Флид М.Р.
Окислительное хлорирование углеводородов. Сообщение 1. Реакция Дикона. Окислительное хлорирование предельных углеводородов С1 и С2
Катализ в промышленности. 2024. №1. С.5-33. DOI: 10.18412/1816-0387-2024-1-5-33 РИНЦ CAPlus OpenAlex

Даты:

Поступила в редакцию:	25 мая 2023 г.
Принята к публикации:	17 окт. 2023 г.
Опубликована online:	18 сент. 2024 г.

Идентификаторы БД:

Web of science:	WOS:001315700900004
Scopus:	2-s2.0-85204775415
РИНЦ:	69201078
OpenAlex:	W4402716791

Альметрики: