Sciact
  • EN
  • RU

Influence of Support Properties on the State and Activity of Supported Palladium in the Decomposition Reaction of Hydrazine Monohydrate Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2024, Том: 65, Номер: 4, Страницы: 396-404 Страниц : 9 DOI: 10.1134/s0023158424601748
Авторы Matyshak V.A. , Silchenkova O.N. , Ilichev A.N. , Bykhovsky M.Ya. , Bychkov V.Yu.
Организации
1 Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia
Реферат: The paper compares the properties and activity of palladium clusters deposited on aluminum oxides of different phase compositions obtained by different methods. The numbers of palladium atoms available for the adsorption of hydrazine were determined for each catalyst. A correlation was found between the number of such atoms and the rate of hydrogen formation in the decomposition reaction of hydrazine monohydrate. It was concluded that an active palladium catalyst for the decomposition of hydrazine can be obtained using a modified support with a large specific surface area. The specific surface area and its modification determined the surface coverage with the active reagent. Obviously, the study of the role of various properties of supports in the formation of the active phase should be continued.
Библиографическая ссылка: Matyshak V.A. , Silchenkova O.N. , Ilichev A.N. , Bykhovsky M.Y. , Bychkov V.Y.
Influence of Support Properties on the State and Activity of Supported Palladium in the Decomposition Reaction of Hydrazine Monohydrate
Kinetics and Catalysis. 2024. V.65. N4. P.396-404. DOI: 10.1134/s0023158424601748 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 14 дек. 2023 г.
Принята к публикации: 27 мар. 2024 г.
Опубликована online: 4 сент. 2024 г.
Идентификаторы БД:
Web of science: WOS:001306479500008
Scopus: 2-s2.0-85203054640
РИНЦ: 69094925
Chemical Abstracts: 2024:1909930
Chemical Abstracts (print): 188:194968
OpenAlex: W4402242966
Альметрики: