Реферат: The Co/BEA zeolite catalyst was found to exhibit exceptionally high activity in ozone catalytic oxidation (OZCO) of methane impurities in air, and it provided CH4 conversion >85% in the temperature range 90–170°С at a high gas hourly space velocity (100 000 h–1). A comparative study of the catalytic performance of 0.5% Co/BEA, 5% Co/BEA, and 5% Co/SiO2 samples was performed for elucidating the nature of the active sites on which the process takes place. The comparison of the catalytic data with the results of catalyst characterization by electron microscopy, UV spectroscopy, X-ray diffraction analysis, and temperature-programmed reduction allowed us to conclude that the active sites of low-temperature methane oxidation are Co2+ ions located in the cationic positions of the zeolite framework, and the 0.5% Co/BEA catalyst had the highest activity in methane oxidation.

Библиографическая ссылка: Bokarev D.A. , Paramoshin I.V. , Kanaev S.A. , Baeva G.N. , Rassolov A.V. , Stakheev A.Y.
Low-Temperature O3-Catalytic Oxidation of Methane on Cobalt-Containing Zeolite Catalysts
Kinetics and Catalysis. 2024. V.65. N4. P.417-420. DOI: 10.1134/s0023158424601736 WOS Scopus РИНЦ CAPlusCA OpenAlex

Даты:

Поступила в редакцию:	9 апр. 2024 г.
Принята к публикации:	2 мая 2024 г.
Опубликована online:	4 сент. 2024 г.

Идентификаторы БД:

Web of science:	WOS:001306479500011
Scopus:	2-s2.0-85203079865
РИНЦ:	69094931
Chemical Abstracts:	2024:1909932
Chemical Abstracts (print):	188:126072
OpenAlex:	W4402243316

Альметрики: