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Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2024, Том: 65, Номер: 5, Страницы: 586-596 Страниц : 11 DOI: 10.1134/s0023158424601943
Авторы Kurnosenko S.A. , Silyukov O.I. , Rodionov I.A. , Minich I.A. , Ustinova A.I. , Zvereva I.A.
Организации
1 Institute of Chemistry, Saint Petersburg State University, 199034, St. Petersburg, Russia
Реферат: In conditions of depletion of mineral reserves, plant biomass is considered a renewable natural resource that can be photocatalytically processed to produce energy-intensive and environmentally friendly hydrogen fuel. In this regard, the present article focuses on the improvement of photocatalytic activity of the layered perovskite-structured niobate HCa2Nb3O10 in the reactions of hydrogen production from aqueous solutions of typical plant biomass components, glucose and xylose, via its exfoliation into nanosheets followed by their reassembly and modification with a Pt cocatalyst. The reassembled compound obtained was shown to outperform in the activity the initial niobate and reference photocatalyst TiO2 P25 Degussa up to 6.3 and 5.3 times, respectively, providing a hydrogen production rate up to 24.2 mmol h−1g−1 and apparent quantum efficiency up to 10% in the mid-near ultraviolet range.
Библиографическая ссылка: Kurnosenko S.A. , Silyukov O.I. , Rodionov I.A. , Minich I.A. , Ustinova A.I. , Zvereva I.A.
Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products
Kinetics and Catalysis. 2024. V.65. N5. P.586-596. DOI: 10.1134/s0023158424601943 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 16 мая 2024 г.
Принята к публикации: 11 июн. 2024 г.
Опубликована online: 4 нояб. 2024 г.
Идентификаторы БД:
Web of science: WOS:001347916900005
Scopus: 2-s2.0-85208606812
РИНЦ: 74496932
Chemical Abstracts: 2024:2418703
OpenAlex: W4404024566
Цитирование в БД:
БД Цитирований
Scopus 1
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