Kinetics and Thermodynamics of Liquid Phase Isomerization of α- and β-Pinene over Pd/C Catalyst Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2008, Том: 95, Номер: 1, Страницы: 161-174 Страниц : 14 DOI: 10.1007/s11144-008-5406-3 | ||
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| Организации |
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Реферат:
The kinetics and thermodynamics of the liquid phase isomerization of an α- and β-pinene mixture on a Pd/C catalyst were studied. The effects of pinene concentration, catalyst particle size, stirring rate, reaction temperature (293–423 K) and hydrogen pressure (0.5–11 bar) on the rate of α- and β-pinene isomerization were investigated. The reaction rate of the α-pinene isomerization has the first order with respect to the α-pinene concentration and 0.5 order with respect to the hydrogen pressure. The thermodynamic parameters of the isomerization (Gibbs energy, reaction enthalpy and reaction entropy) and the equilibrium ratio of pinenes under the conditions studied were determined. The general scheme of the reaction mechanism of α- and β-pinene isomerization over the Pd/C catalyst was proposed.
Библиографическая ссылка:
Deliy I.V.
, Simakova I.L.
Kinetics and Thermodynamics of Liquid Phase Isomerization of α- and β-Pinene over Pd/C Catalyst
Reaction Kinetics and Catalysis Letters. 2008. V.95. N1. P.161-174. DOI: 10.1007/s11144-008-5406-3 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Kinetics and Thermodynamics of Liquid Phase Isomerization of α- and β-Pinene over Pd/C Catalyst
Reaction Kinetics and Catalysis Letters. 2008. V.95. N1. P.161-174. DOI: 10.1007/s11144-008-5406-3 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact
Даты:
| Поступила в редакцию: | 1 сент. 2008 г. |
| Принята к публикации: | 5 сент. 2008 г. |
| Опубликована в печати: | 1 окт. 2008 г. |
| Опубликована online: | 17 дек. 2008 г. |
Идентификаторы БД:
| Web of science: | WOS:000260113900020 |
| Scopus: | 2-s2.0-57649158363 |
| РИНЦ: | 13574572 |
| Chemical Abstracts: | 2008:1314119 |
| Chemical Abstracts (print): | 150:398719 |
| OpenAlex: | W2012113597 |
| Sciact: | 2120 |