Реферат: The temporal analysis of products (TAP) technique coupled with the oxygen TPD was used to elucidate the effects of the Pt-supported fluorite-like doped ceria–zirconia oxide chemical composition and the type of pretreatment on their oxygen bonding strength, mobility, and reactivity as related to catalytic properties in the partial oxidation of methane into synthesis gas. A rapid evolution of hydrogen under CH4 pulse observed for oxidized catalysts agrees with the direct route of the methane selective oxidation into syngas. This route is favored by the Pt-support interaction and a moderate bonding strength of surface oxygen species along with a high lattice oxygen mobility.

Библиографическая ссылка: Gubanova E.L. , Sadykov V.A. , van Veen A.C. , Mirodatos C.
Tap Study of the Impact of the Oxidation State of Pt/PrCeZrO and Pt/GdCeZrO Catalysts on Their Reactivity in the Partial/Deep Oxidation of Methane
Reaction Kinetics and Catalysis Letters. 2009. V.97. N2. P.349-354. DOI: 10.1007/s11144-009-0040-2 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Даты:

Поступила в редакцию:	27 июн. 2008 г.
Принята к публикации:	28 апр. 2009 г.
Опубликована online:	14 июл. 2009 г.
Опубликована в печати:	1 авг. 2009 г.

Идентификаторы БД:

Web of science:	WOS:000268445800026
Scopus:	2-s2.0-68249105605
РИНЦ:	13614361
Chemical Abstracts:	2009:915304
Chemical Abstracts (print):	154:517078
OpenAlex:	W2038952966
Sciact:	3047

Цитирование в БД:

БД	Цитирований
Scopus	5
OpenAlex	3

Альметрики: