Activation of Bis(pyrrolylaldiminato) and (Salicylaldiminato)(pyrrolylaldiminato) Titanium Polymerization Catalysts with Methylalumoxane

Activation of Bis(pyrrolylaldiminato) and (Salicylaldiminato)(pyrrolylaldiminato) Titanium Polymerization Catalysts with Methylalumoxane Научная публикация

Журнал

Organometallics
ISSN: 0276-7333 , E-ISSN: 1520-6041

Вых. Данные

Год: 2007, Том: 26, Номер: 2, Страницы: 288-293 Страниц : 6 DOI: 10.1021/om0607752

Авторы

Bryliakov Konstantin P. ¹ , Kravtsov Evgenii A. ¹ , Broomfield Lewis ² , Talsi Evgenii P. ¹ , Bochmann Manfred ²

Организации

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
2	Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, United Kingdom

Activation of pyrollylaldiminato titanium complexes (N−N)2TiCl2 and of heteroligated (N−N)(N−O)TiCl2 with 13C-MAO leads to outer-sphere ion pairs [L‘LTiMe(S)]+[MeMAO]-, which rapidly polymerize 13C2H4. The catalysts show significant differences in deactivation pathways.

Bryliakov K.P. , Kravtsov E.A. , Broomfield L. , Talsi E.P. , Bochmann M.
Activation of Bis(pyrrolylaldiminato) and (Salicylaldiminato)(pyrrolylaldiminato) Titanium Polymerization Catalysts with Methylalumoxane
Organometallics. 2007. V.26. N2. P.288-293. DOI: 10.1021/om0607752 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Поступила в редакцию:	25 авг. 2006 г.
Опубликована online:	9 дек. 2006 г.
Опубликована в печати:	1 янв. 2007 г.

Web of science:	WOS:000243339300007
Scopus:	2-s2.0-33846647018
РИНЦ:	13558612
Chemical Abstracts:	2006:1288455
Chemical Abstracts (print):	146:206406
OpenAlex:	W2090245173
Sciact:	18633

БД	Цитирований
Scopus	29
OpenAlex	29