Реферат: A family of novel catalysts for oxygen electroreduction is presented, based on nanostructured RuxXy chalcogenide compounds (X=S, Se, Te). EXAFS data suggest that the catalysts have a core of ruthenium atoms, which has triangular co-ordination and a direct metalmetal bond. Depending on the chalcogen, the Ru-cluster consists of two or three metal layers of different size and mutual co-ordination with chalcogen atoms co-ordinated to the periphery of the cluster. Variation of the chalcogen type affects the size of the Ru-cluster and the strength of its interaction with the chalcogen. This influences the interaction of Ru-clusters with oxygen and thus their activity in the reduction of molecular oxygen.

Библиографическая ссылка: Alonso-Vante N. , Malakhov I.V. , Nikitenko S.G. , Savinova E.R. , Kochubey D.I.
The Structure Analysis of the Active Centers of Ru-Containing Electrocatalysts for the Oxygen Reduction. An in situ EXAFS Study
Electrochimica Acta. 2002. V.47. N22-23. P.3807-3814. DOI: 10.1016/S0013-4686(02)00351-1 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Даты:

Поступила в редакцию:	17 окт. 2001 г.
Опубликована online:	8 авг. 2002 г.
Опубликована в печати:	30 авг. 2002 г.

Идентификаторы БД:

Web of science:	WOS:000178071500024
Scopus:	2-s2.0-0037200144
РИНЦ:	13399517
Chemical Abstracts:	2002:662439
Chemical Abstracts (print):	138:46224
OpenAlex:	W2013869280
Sciact:	7570

Цитирование в БД:

БД	Цитирований
Scopus	101
OpenAlex	87

Альметрики: