Реферат: The addition of ethylene to Al(CH3)3, AlH3, (CH3)2AlH and β-elimination of olefin from (CH3)2AlC3H7 have been studied using the MINDO/3 method. The addition reaction over Al-C and Al-H bonds has been shown to proceed via a two-stage mechanism, which includes the formation of an intermediate π-complex with further cis-insertion of coordinated olefin. The nature of the activation energy is determined by the rearrangement of the active center structure at the coordination stage, and on the rupture of the π-bond of coordinated olefin at the stage of insertion. Different insertion reactivities of olefin over the M-L bond (where M = a transition or non-transition metal, L = alkyl or hydrogen) was interpreted by analysis of the orbital symmetry of the transition state.

Библиографическая ссылка: Zakharov I.I. , Zakharov V.A.
Quantum-Chemical Study of Ethylene Oligomerization in the Presence of Indvidual Organoaluminium Compounds
Journal of Molecular Catalysis. 1982. V.14. N2. P.171-184. DOI: 10.1016/0304-5102(82)80035-7 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Даты:

Поступила в редакцию:	3 дек. 1980 г.
Опубликована в печати:	1 февр. 1982 г.
Опубликована online:	2 окт. 2001 г.

Идентификаторы БД:

Web of science:	WOS:A1982NA11200002
Scopus:	2-s2.0-0020087511
РИНЦ:	28815315
Chemical Abstracts:	1982:121924
Chemical Abstracts (print):	96:121924
OpenAlex:	W2077346819
Sciact:	12798

Цитирование в БД:

БД	Цитирований
Scopus	12
OpenAlex	10

Альметрики: