Реферат: Adsorption and decomposition of ethylene as well as deposition of graphite on the (110) plane of platinum in the temperature range from 300 to 1450 K are studied by XPS, LEED, and TPR. It is shown that the process of ethylene decomposition proceeds through a number of intermediate species up to elementary carbon. At a temperature higher than 470 K there is penetration of the carbon into subsurface layers of platinum. This process is accompanied by the formation of a carbide-like phase of sandwich structure (CLPSS) stable at T⩽700 K responsible for modifying the surface properties. It is found that the mechanism of low-temperature graphite formation on Pt(110) is determined mainly by the decomposition of the CLPSS at T>700 K. The role of different parameters influencing the efficiency of the graphitization is discussed.

Библиографическая ссылка: Boronin A.I. , Bukhtiyarov V.I. , Kvon R. , Chesnokov V.V. , Buyanov R.A.
Decomposition of Ethylene and a Mechanism of Graphite Formation on the Pt(110) Surface
Surface Science. 1991. V.258. N1-3. P.289-301. DOI: 10.1016/0039-6028(91)90923-G WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Даты:

Поступила в редакцию:	31 янв. 1991 г.
Принята к публикации:	29 мая 1991 г.
Опубликована в печати:	2 нояб. 1991 г.
Опубликована online:	19 сент. 2002 г.

Идентификаторы БД:

Web of science:	WOS:A1991GQ63300037
Scopus:	2-s2.0-0026414393
РИНЦ:	31085462
Chemical Abstracts:	1992:58581
Chemical Abstracts (print):	116:58581
OpenAlex:	W1993745838
Sciact:	14582

Цитирование в БД:

БД	Цитирований
Scopus	34
OpenAlex	36

Альметрики: