Meerwein–Ponndorf–Verley–Oppenauer Non-catalytic Reaction of Monoterpenoids in Supercritical Fluids

Meerwein–Ponndorf–Verley–Oppenauer Non-catalytic Reaction of Monoterpenoids in Supercritical Fluids Научная публикация

Журнал

Russian Journal of Physical Chemistry B
ISSN: 19907931 , E-ISSN: 19907923

Вых. Данные

Год: 2019, Том: 13, Номер: 7, Страницы: 1117-1120 Страниц : 4 DOI: 10.1134/S1990793119070054

Авторы

Philippov A.A. ^1,2 , Chibiryaev A.M. ^1,2

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Novosibirsk State University, Novosibirsk, 630090 Russia

The Meerwein–Ponndorf–Verley–Oppenauer non-catalytic reaction of cyclic monoterpenic ketones and alcohols (menthone, camphor, menthol, and borneol) was studied under supercritical conditions. It has been showed that the ketones can be reduced in supercritical isopropanol with high selectivity (89–98%) without any catalyst or base. At the same time, the conversion of menthone was 63% at 350°C, and that of camphor was 11% at 300°C for 5 h reaction. The conversions of menthol and borneol in the reverse dehydrogenation reaction in supercritical acetone were 34 and 22%, respectively, and the selectivities were 95 and 88%. Thermal dehydration is a main side reaction for all the reactions. © 2019, Pleiades Publishing, Ltd.

Philippov A.A. , Chibiryaev A.M.
Meerwein–Ponndorf–Verley–Oppenauer Non-catalytic Reaction of Monoterpenoids in Supercritical Fluids
Russian Journal of Physical Chemistry B. 2019. V.13. N7. P.1117-1120. DOI: 10.1134/S1990793119070054 WOS Scopus РИНЦ CAPlus OpenAlex Sciact

Поступила в редакцию:	11 сент. 2018 г.
Принята к публикации:	29 сент. 2018 г.
Опубликована в печати:	1 дек. 2019 г.
Опубликована online:	27 февр. 2020 г.

Web of science:	WOS:000519387800007
Scopus:	2-s2.0-85080123397
РИНЦ:	43244620
Chemical Abstracts:	2020:448715
OpenAlex:	W3008967790
Sciact:	34942

БД	Цитирований
OpenAlex	2