Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes

Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes Научная публикация

Журнал

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Вых. Данные

Год: 2012, Том: 14, Номер: 17, Страницы: 4310-4313 Страниц : 4 DOI: 10.1021/ol3015122

Авторы

Ottenbacher Roman V. ¹ , Samsonenko Denis G. ² , Talsi Evgenii P. ³ , Bryliakov Konstantin P. ³

Организации

1	Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation
2	Nikolaev Institute of Inorganic Chemistry, Pr. Lavrentieva 3, Novosibirsk 630090, Russian Federation
3	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russian Federation

Aminopyridine manganese complexes [LMnII(OTf)2] having a similar coordination topology catalyze the oxidation of unactivated aliphatic CH groups with H2O2, demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).

Ottenbacher R.V. , Samsonenko D.G. , Talsi E.P. , Bryliakov K.P.
Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes
Organic Letters. 2012. V.14. N17. P.4310-4313. DOI: 10.1021/ol3015122 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Поступила в редакцию:	3 мая 2012 г.
Опубликована online:	2 июл. 2012 г.
Опубликована в печати:	7 сент. 2012 г.

Web of science:	WOS:000308390000004
Scopus:	2-s2.0-84866034562
РИНЦ:	20480428
Chemical Abstracts:	2012:949357
Chemical Abstracts (print):	157:356068
OpenAlex:	W2327161573
Sciact:	512

БД	Цитирований
OpenAlex	130