Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism

Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism Обзор

Конференция

11th European Workshop on Selective Oxidation - Selectivity in Oxidation - Key to New Resources Valorization (ISO) during the 12th European Congress on Catalysis - Balancing the Use of Fossil and Renewable Resources (Europacat)
30 авг. - 4 сент. 2015 , Kazan

Журнал

Catalysis Today
ISSN: 0920-5861

Вых. Данные

Год: 2016, Том: 278, Номер: Part 1, Страницы: 30-39 Страниц : 10 DOI: 10.1016/j.cattod.2016.04.033

Авторы

Ottenbacher Roman V. ^1,2 , Talsi Evgenii P. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russia
2	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russia

This mini-review summarizes the progress in the asymmetric epoxidation of olefins in the presence of manganese aminopyridine complexes, achieved in the last decade. The major breakthroughs in catalyst design, that eventually led to the emergence of highly enantioselective (> 99% ee) and efficient (> 1000 TON) catalysts, are discussed. The mechanistic studies carried out in recent years are given particular attention.

Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism
Catalysis Today. 2016. V.278. NPart 1. P.30-39. DOI: 10.1016/j.cattod.2016.04.033 WOS Scopus РИНЦ CAPlusCA OpenAlex Sciact

Поступила в редакцию:	17 нояб. 2015 г.
Принята к публикации:	25 апр. 2016 г.
Опубликована online:	12 мая 2016 г.
Опубликована в печати:	1 дек. 2016 г.

Web of science:	WOS:000388053000004
Scopus:	2-s2.0-84992736484
РИНЦ:	28170041
Chemical Abstracts:	2016:748637
Chemical Abstracts (print):	165:499763
OpenAlex:	W2364384387
Sciact:	9197

БД	Цитирований
OpenAlex	28