Rh- and Rh–Ni–MgO-Based Structured Catalysts for on-Board Syngas Production via Gasoline Processing

Rh- and Rh–Ni–MgO-Based Structured Catalysts for on-Board Syngas Production via Gasoline Processing Научная публикация

Конференция

XV HYdrogen POwer THeoretical and Engineering Solutions International Symposium
03-05 июн. 2020 , Cape-Town (Online)

Журнал

International Journal of Hydrogen Energy
ISSN: 0360-3199

Вых. Данные

Год: 2021, Том: 46, Номер: 72, Страницы: 35840-35852 Страниц : 13 DOI: 10.1016/j.ijhydene.2021.01.183

Авторы

Ruban N.V. ^1,2 , Potemkin D.I. ^1,2,3 , Rogozhnikov V.N. ^1,2,4 , Shefer K.I. ¹ , Snytnikov P.V. ^1,2 , Sobyanin V.A. ¹

Организации

1	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Pirogova St., 2, Novosibirsk, 630090, Russia
3	Novosibirsk State Technical University, Karl Marx Pr., 20, Novosibirsk, 630073, Russia
4	Gubkin Russian State University of Oil and Gas, Leninsky Pr., 65, Moscow, 119991, Russia

Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl FeCrAlloy wire mesh supported catalysts were prepared via multistep procedure. They were characterized by XRD, SEM and TEM techniques. A comparative study of autothermal reforming (ATR) of isooctane and simulated gasoline (blends of isooctane, ortho-xylene and naphthalene) over Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl was performed. Both catalysts showed excellent performance in ATR of isooctane at molar ratios of O2:C = 0.51 and H2O:C = 2.59, T = 750°С and GHSV = 10000 h−1. In the ATR of isooctane – o-xylene blend in presence of Rh–Ni-containing catalyst carbon formation was observed. Rh-containing catalyst demonstrated rather good activity and stability even in the case of isooctane – o-xylene – naphthalene blend.

Ruban N.V. , Potemkin D.I. , Rogozhnikov V.N. , Shefer K.I. , Snytnikov P.V. , Sobyanin V.A.
Rh- and Rh–Ni–MgO-Based Structured Catalysts for on-Board Syngas Production via Gasoline Processing
International Journal of Hydrogen Energy. 2021. V.46. N72. P.35840-35852. DOI: 10.1016/j.ijhydene.2021.01.183 WOS Scopus РИНЦ CAPlus OpenAlex Sciact

Поступила в редакцию:	15 окт. 2020 г.
Принята к публикации:	26 янв. 2021 г.
Опубликована online:	25 февр. 2021 г.
Опубликована в печати:	1 окт. 2021 г.

Web of science:	WOS:000706475100010
Scopus:	2-s2.0-85101513329
РИНЦ:	46749308
Chemical Abstracts:	2021:407157
OpenAlex:	W3130198979
Sciact:	44339

БД	Цитирований
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